Catalytic oxidation-reduction hydration of olefin with molecular oxygen in the presence of bis(1,3-diketonato)cobalt(II) complexes.
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概要
- 論文の詳細を見る
In the presence of a bis(1,3-diketonato)cobalt(II) complex, various olefins are converted to the corresponding hydrated products according to the Markownikov rule on treatment with molecular oxygen in secondary alcohol ("oxidation–reduction hydration"). Removal of water formed during the hydration reaction, especially by azeotropic method, is remarkably effective to improve yields of the hydrated products based on the cobalt(II) catalyst as bis(trifluoroacetylacetonato)cobalt(II) (Co(tfa)<SUB>2</SUB>) or bis(2-ethoxycarbonyl-3-oxobutanalato)cobalt(II) (Co(ecbo)<SUB>2</SUB>).
- 公益社団法人 日本化学会の論文
著者
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Yamada Tohru
Basic Research Laboratories For Organic Synthesis Mitsui Petrochemical Industries Ltd.
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TAKAI Toshihiro
Basic Research Laboratories for Organic Synthesis, Mitsui Petrochemical Industries, Ltd.
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KATO Koji
Basic Research Laboratories for Organic Synthesis, Mitsui Petrochemical Industries, Ltd.
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Kato Koji
Basic Research Laboratories For Organic Synthesis Mitsui Petrochemical Industries Ltd.
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Inoki Satoshi
Basic Research Laboratories for Organic Synthesis, Mitsui Petrochemical Industries, Ltd.
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Isayama Shigeru
Basic Research Laboratories for Organic Synthesis, Mitsui Petrochemical Industries, Ltd.
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