A novel synthesis of 4B-element-containing styrene derivatives.
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概要
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To synthesize 4B-group element-containing styrene monomers, alkylmetalation reactions of 4-methylstyrene (<B>1</B>) in the presence of lithium diisopropylamide (<B>2</B>) were investigated. Trialkylsilylation of <B>1</B> proceeded easily by the reaction with trialkylsilyl chloride in the presence of <B>2</B> to form mono- and bis-trialkylsilylated methylstyrene. This synthetic method was expanded to other 4B-element-containing styrenes such as germyl and stannyl compounds.
- 公益社団法人 日本化学会の論文
著者
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Nagasaki Yukio
Department Of Internal Medicine Sapporo Medical College
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TSURUTA Teiji
Department of Industrial Chemistry, Science University of Tokyo
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Kurosawa Koichi
Department of Industrial Chemistry, Faculty of Engineering, Science University of Tokyo
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Tsuruta Teiji
Department of Industrial Chemistry, Faculty of Engineering, Science University of Tokyo
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Nagasaki Yukio
Department of Industrial Chemistry, Faculty of Engineering, Science University of Tokyo
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