Tentative reaction network for bromate-bromide-ferroin system and simulation of behavior of the system under batch reactor and continuous-flow stirred tank reactor conditions.
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One tentative reaction network for the bromate–bromide–tris(1,10-phenanthroline)iron(II) (ferroin) system in an acidic medium was examined by means of a simulation method, which involved the Field–Körös–Noyes scheme, the reduction of HBrO<SUB>2</SUB> and HOBr by ferroin via two-electron transfer processes and the reactions of Fe(phen)<SUB>2</SUB><SUP>2+</SUP> with BrO<SUB>3</SUB><SUP>−</SUP>, HBrO<SUB>2</SUB>, HOBr, and BrO<SUB>2</SUB>·. The network successfully reproduced the behavior of the system in a batch reactor. The behavior of the system in a continuous-flow stirred tank reactor (CSTR) was simulated under two CSTR conditions: 1) Bromide flowed into the CSTR, and 2) bromide did not flow into the CSTR. Under the former condition, the system exhibited bistability and sustained oscillations. The calculated oscillations were of small amplitude and high frequency. Under the latter condition, the system exhibited bistability.
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