Photolysis of diaryl triphenylmethylphosphonates.
スポンサーリンク
概要
- 論文の詳細を見る
Synopsis. Upon UV irradiation in methanol,diaryl triphenylmethylphosponate underwent three types of elimination of two aryl groups to give biaryls: the first is an α,α-elimination of two phenyl groups from a triphenylmethyl group which leads to formation of the corresponding carbene intermidiate; the second is an elimination of two aryl groups from a diaryl ester group to afford biaryl; the third is an elimination of phenyl and aryl groups from both moieties to give arylbenzene.
著者
-
Takamuku Setsuo
Institute For Scienctific And Industrial Research Osaka University
-
Shi Min
Institute of Scientific and Industrial Research Osaka University
-
Okamoto Yoshiki
Institute of Scientific and Industrial Research Osaka University
-
Takamuku Setsuo
Institute of Scientific and Industrial Research Osaka University
関連論文
- Physicochemical Properties of 2-Methylthio-4-Methylphenol, a Model Compound of the Novel Cofactor of Galactose Oxidase
- A New Approach to Study of Solvent Effect on Intramolecular Electron Transfer
- Evidence for Parallel Photoinduced Electron Transfer in Diquinone Substituted Porphyrins
- Photooxygenation of 1,1-Diarylethylenes via Addition of Oxygen to the 1,4-Dimer Radical Cations, Catalyzed by 10-Methylacridinium Ion
- Photoinduced Hydride Reduction of 10-Methylacridinium Ion by Alkylbenzenes in the Presence of Perchloric Acid
- Photoreactivities of Contact Charge-Transfer Complexes between 1,1-Diarylethenes and Oxygen Molecules. Dimerization and Oxygenation Accelerated in Medium Polar Solvent
- Cycloreversion of 1-(1-Naphthyl)-5-phenylbicyclo[3.2.0]hept-6-ene to 1-(1-Naphthyl)-4-phenyl-1,3-cycloheptadiene by Triplet Sensitization and Direct Irradiation
- 1,3-Diplolar Additions of a Nitrile Ylide with Carbonyl Compounds Studied by Laser Flash Photolysis of 3-(Biphenyl-4-yl)-2H-azirine
- Stilbene Dimer Radical Cations in the Radiolyses of Stilbenes and 1,2,3,4-Tetraphenylcyclobutanes
- Mechanism of the cis- and trans-anti-Markovnikov Addition of Methanol to 1-Phenycycloalkenes through Photoinduced Electron Transfer
- Mechanism of Photochemical Reaction of Contact Charge Transfer Pair between 1, 1-Diarylethene and Oxygen
- Radical Anion of Nitrile Ylide by Dual Beam Irradiation of 3-(4-Biphenylyl)-2H-azirine at Low Temperature
- Cycloreversion of 1,4-Diphenylbicyclo[3.2.0]hept-2-ene via Triplet State. Evidence for Adiabatic Process on the Triplet Surface
- Photolyses of Derivatives of Naphthyl and Anthryl Phosphates and Methylphosphonates
- Photolysis of diaryl triphenylmethylphosphonates.