The dissociation equilibrium of the copper(II) acetate dimer in acetic acid.

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概要

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• The dissociation equilibrium of the copper(II) acetate dimer in acetic acid was studied by means of high-sensitivity spectorophotometry. The dissociation constant of the nonaquated dimer was determined to be <I>K</I><SUB>dis</SUB>=10<SUP>−6.2±0.2</SUP> at 25 °C. The dissociation was promoted in the presence of water. The formation constant of the monoaquated monomer was estimated to be <I>K</I><SUB>ml</SUB>=3.0.

• 公益社団法人 日本化学会の論文

著者

• SUZUKI Toshio

  Laboratory of Analytical Chemistry, Faculty of Science, Niigata University

• Sawada Kiyoshi

  Laboratory Of Analytical Chemistry Faculty Of Science Niigata University

• Kikuchi Yoichi

  Laboratory of Analytical Chemistry, Faculty of Science, Niigata University

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