Electrochemical polymerization of N-trimethylsilylpyrrole and other substituted pyrroles which contain Si or Ge atom(s) in their monomer structures.
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概要
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<I>N</I>-Trimethylsilylpyrrole and three new compounds; <I>N</I>-trimethylgermylpyrrole, <I>N</I>-chloromethyldimethylsilylpyrrole, and <I>N</I>-pentamethyldisilanylpyrrole, were synthesized. These four monomers were electrochemically polymerized and four new organic conducting polymers were obtained. Resulting polymers had good film producibility and conductivity as high as that for polypyrrole. They showed three distinguishable colors at different potentials: blue in the doped state, yellow in the undoped state, and reddish color in between.
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