Synthesis and square planar-octahedral equilibrium of bismacrocyclic dinickel(II) complexes with polymethylene bridges of various lengths.
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概要
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A new series of binuclear nickel(II) complexes with bis(tetraazamacrocycle), 7,7′-polymethylenebis[3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene]dinickel(II) perchlorates with polymethylene bridges with a length of 2–6-C, was synthesized, as well as the corresponding free ligands. The dinickel(II) complexes were found to be in equilibrium between square planar and octahedral forms in water. The equilibrium shifts toward the octahedral side as the polymethylene bridge becomes short.
- 公益社団法人 日本化学会の論文
著者
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Mochizuki Katsura
Department Of Chemistry Faclty Of Science And Graduate School Of Integrated Science Yokohama City Un
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Ikeda Yosihito
Department of Chemistry, Yokohama City University
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- Determination of hyperoxide in dimethyl sulfoxide by photometric titration with iodine.
- Synthesis and square planar-octahedral equilibrium of bismacrocyclic dinickel(II) complexes with polymethylene bridges of various lengths.
- Synthesis of (6-(1,4,7,10-Tetraaza-12-cyclotridecyl)-1,4,8,11-tetraazacyclotetradecane)dinickel(II) Perchlorate and Its Electrocatalytic Property for Water Reduction.