Fractal pattern formation of metal-containing polymeric thin films prepared by plasma reaction.
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概要
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Three kinds of metal-containing polymeric thin films were obtained from copper acetylacetonate (CuAA), titanium tetraisopropoxide (TiTP) and tetramethyltin (TMT) by plasma polymerization. The vaporized metal-organic compounds underwent chemical rearrangement under the action of energetic plasma to give higher ordered thin films consisting of metal and organic polymer layers. Transmission electron microscopy (TEM) photographs of the films consisting of alternative metal and organic regions showed fractal pattern. The fractal dimensions were calculated as 1.87 for CuAA, 1.94 for TiTP and 1.92 for TMT films, respectively. Formation process of fractal pattern was discussed in terms of chemical structure of starting compounds and plasma conditions.
- 公益社団法人 日本化学会の論文
著者
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Yamada Katsuyuki
Department Of Radiology Osaka City University Medical School.
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OSADA Yoshihito
Department of Biological Science, Graduate School of Science, Hokkaido University
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Gong Jianping
Department of Chemistry, Ibaraki University
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Kagami Yoshiharu
Department of Chemistry, Ibaraki University
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Yamada Katsuyuki
Department of Chemistry, Ibaraki University
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