Stereochemistry of thermal chlorine-for-bromine substitution in diastereomeric 3-bromo-4-fluorohexane.

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概要

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• The stereochemistry of thermalized chlorine-for-bromine substitution was studied in gaseous (3<I>RS</I>,4<I>SR</I>)- and (3<I>RS</I>,4<I>RS</I>)-3-bromo-4-fluorohexane. While energetic chlorine-for-bromine substitution occurs by a two-channel substitution mechanism, one leading to retention, the other to inversion of configuration, thermal chlorine-for-bromine substitution at the sp<SUP>3</SUP>-hybridized carbon of the diastereomers proceeds extensively, if not exclusively, via stereochemical inversion.

• 公益社団法人 日本化学会の論文

著者

• SHARMA Ram

  Department of Biochemistry. University of Southampton

• Meyer Richard

  Medical Research, V.A. Medical Center

• Rack Edward

  Department of Chemistry, University of Nebraska-Lincoln

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• Stereochemistry of thermal chlorine-for-bromine substitution in diastereomeric 3-bromo-4-fluorohexane.

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