Reaction mechanism between pyruvic acid and aromatic amines.

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概要

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• The formation of the condensation products obtained when pyruvic acid and aromatic amines are allowed to react, can be explained by condensation of one mole of the imine of pyruvic acid with one mole of the enamine isomer, either through the C atom or through the N atom, followed by elimination and lactonization to give a γ-lactone carboxylate or an azlactone carboxylate, which on decarboxylation give an iminobutanolide or an azlactone respectively. Aminolysis of these cyclic intermediates led to the formation of the final products.

• 公益社団法人 日本化学会の論文

著者

• Moran J.

  Department Of Surgery. Faculty Of Medicine Universidad De Extremadura

• Grande M.

  Department of Organic Chemistry, F. C. Químicas, University of Salamanca

• Tapia I.

  Department of Organic Chemistry, F. C. Químicas, University of Salamanca

• Alcázar V.

  Department of Organic Chemistry, F. C. Químicas, University of Salamanca

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• Reaction mechanism between pyruvic acid and aromatic amines.

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