Catalysis of .ALPHA.-Fe and Fe1-xS toward the hydrogenolysis of trans-stilbene in hydroaromatic hydrocarbon solvents.

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概要

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• The Fe-catalyzed hydrogenolysis of <I>trans</I>-stilbene was carried out in aromatic hydrocarbon solvents at 380 °C. α-Fe and pyrrhotite catalyze bimolecular hydrogen transfer from hydroaromatic hydrocarbons to <I>trans</I>-stilbene and hydroaromatic hydrocarbon-mediated hydrogenolysis of <I>trans</I>-stilbene by molecular hydrogen at 380 °C. This catalyzed hydrogen transfer proceeds by radical mechanism. The product distribution is affected by the catalyst species. Pyrrhotite catalyzes the hydrogenation of <I>trans</I>-stilbene more effectively than α-Fe. Both the iron catalysts are inactive toward the cleavage of carbon to carbon single bond in bibenzyl.

• 公益社団法人 日本化学会の論文

著者

• Fujimoto Ken-ichiro

  Department of Reaction Chemistry, Faculty of Engineering, The University of Tokyo

関連論文

• Catalysis of .ALPHA.-Fe and Fe1-xS toward the hydrogenolysis of trans-stilbene in hydroaromatic hydrocarbon solvents.

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