Synthetic inorganic ion-exchange materials LX. Ion exchange and chromatographic separation of alkali metal ions on cubic ammonium molybdate-A novel cation exchanger.
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概要
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The ion-exchange selectivity of H<SUP>+</SUP>-form of cubic ammonium molybdate (H-CAM) was studied for alkali metal ions in both HNO<SUB>3</SUB> and NH<SUB>4</SUB>NO<SUB>3</SUB> media. Ideal ion-exchange reaction was observed in both the media with high selectivity for Rb<SUP>+</SUP> and Cs<SUP>+</SUP>. The selectivity sequence was found to be Li<SUP>+</SUP><Na<SUP>+</SUP><K<SUP>+</SUP><Rb<SUP>+</SUP><Cs<SUP>+</SUP> in accordance with the Eisenman sequence-1 in both the media, with separation factors greater than the commercial polystyrene strong acid exchange resin. Efficient separation of alkali metal ions could be achieved on H-CAM column.
- 公益社団法人 日本化学会の論文
著者
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Khan Abdul
Department Cardiac Of Surgery Dow University Of Health Sciences
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Tsuji Masamichi
Department Of Chemical Science Graduate School Of Natural Science And Technology Kanazawa University
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Abe Mitsuo
Department Of Veterinary Anatomy Rakuno Gakuen University School Of Veterinary Medicine
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KANZAKI Yasushi
Department of Applied Chemistry, Kanagawa Institute of Technology
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