Voltammetric studies on some arylhydrazones of .ALPHA.-cyano ketones and .ALPHA.-cyano esters.

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概要

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• The redox characteristics of the title compounds are extensively studied using DC-, cyclic voltammetry, coulometry, and controlled potential electrolysis in benzonitrile at platinum electrodes. These compounds are oxidized in one-electron transfer process followed by deprotonation which leads to dimerization. The reduction process differs according to the nature of the compound and the electron-withdrawing power of the substituent in the α-position. They can be reduced in a single two electron or two one electron waves leading in both cases to saturation of the hydrazonic moiety.

• 公益社団法人 日本化学会の論文

著者

• ISMAIL N.

  Chemistry Department, Faculty of Science, Zagazig University

関連論文

• 置換チアジアゾール類の電気化学挙動
• Voltammetric studies on some arylhydrazones of .ALPHA.-cyano ketones and .ALPHA.-cyano esters.

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