Hydrogenation of 1,3-butadiene over CaO catalyst treated with methanol.
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概要
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When calcium oxide was treated with methanol at low temperature, calcium methoxides i.e., calcium dimethoxide and, calcium hydroxide methoxide, could be easily formed. The catalyst produced by the thermal decomposition of these compounds exhibited remarkably high activity to the hydrogenation of 1,3-butadiene. With the aim to investigate the cause of the high activity, two other calcium oxide catalysts were used for a comparison. The cause was ascribed to the formation of a large amount of electron-donating sites, including both basic ones and those with a high surface area.
- 公益社団法人 日本化学会の論文
著者
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Matsuda Tsuneo
Department Of Applied Chemistry Faculty Of Engineering Saitama University
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Sugimoto Masatoshi
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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Yoshiara Hiroshi
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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