Study of Various Factors Affecting the Stability of Ternary Cu(II) and Ni(II) Complexes.
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概要
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The stability constants of the ternary M(II) complexes [MAL], where M(II) refers to Cu(II) and Ni(II), A refers to 2,6-pyridinedicarboxylic acid (dpa) and iminodiacetic acid (imda) and L refers to glycine, α-alanine, phenylalanine, tyrosine, tryptophan, ethylenediamine, <B>1</B>,3-propanediamine, oxalic acid, catechol, catechuic acid, tiron, pyrogallol, <I>o</I>-aminophenol, and <I>o</I>-phenylenediamine, have been determined potentiometrically by using SCOGS computer programme. Probable reasons for less negative <I>Δ</I>log<I>K</I> values of the ternary complexes have been discussed.
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著者
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Ullah Mohammd
Department of Chemistry, Faculty of Science, M. S. University of Baroda
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Bhattacharya Pabithrak
Department of Chemistry, Faculty of Science, M. S. University of Baroda