Synthesis and Properties of Peroxy Esters Having a Benzophenone Chromophore.

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概要

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• Diperoxy esters having a benzophenone chromophore have been successfully synthesized from the reaction of 3-chloro-3-phenylphthalide (<B>1</B>) with 2,5-dihydroperoxy-2,5-dimethyl-3-hexyne (<B>4a</B>) or 2,5-dihydroperoxy-2,5-dimethylhexane (<B>4b</B>). The corresponding diperoxy esters had a UV absorption above 300 nm. The free radicals produced during the photolysis of these compounds initiated the radical polymerization of methyl methacrylate at room temperature under UV light.

• 公益社団法人 日本化学会の論文

著者

• Kumura Hiromi

  Chemicals & Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.

• Higuchi Yoshiki

  Chemical & Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.

• Suyama Shuji

  Chemicals & Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.

• Nakamura Tomoyuki

  Chemicals & Explosives Research Laboratory, Nippon Oil & Fats Co., Ltd.

関連論文

• Synthesis and Properties of Peroxy Esters Having a Benzophenone Chromophore.
• Thermal decomposition of 2,2-bis(t-butyldioxy)alkanes.
• A convenient synthesis of 2-t-alkyldioxy-2-methyl-1-propanols.
• Substituent effects in the decomposition of t-alkyl t-butyl peroxides.
• Thermal decomposition of 2,2-bis(t-butyldioxy)-3-methylbutane.

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