Hexaammineruthenium Complex as Two-Electron Catalyst for Oxygen Evolution by Homogeneous and Heterogeneous Water Oxidation
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概要
- 論文の詳細を見る
The [Ru(NH<SUB>3</SUB>)<SUB>6</SUB>]<SUP>3+</SUP> complex is shown to be a two-electron catalyst for homogeneous as well as heterogeneous water oxidation to evolve dioxygen. The oxygen evolution is proposed to proceed by two molecules of the complex through a peroxo-bridged intermediate involving higher oxidation state [Ru<SUP>v</SUP>(NH<SUB>3</SUB>)<SUB>6</SUB>]<SUP>5+</SUP>.
- 公益社団法人 日本化学会の論文
著者
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Kaneko Masao
The Institute Of Biophotochemonics Co. Ltd.
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KIRA Akira
The Institute of Physical and Chemical Research
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Kaneko Masao
The Institute of Physical and Chemical Research (RIKEN)
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Ramaraj Ramasamy
School of Chemistry, Madurai Kamaraj University
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