Cobalt(III)-tren complexes of 3-formylcamphor.
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概要
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3-Formylcamphor Co(III) complexes of a tripod-like ligand, tren, were prepared and the two possible geometrical isomers were separated successfully. The crystal structure of one of them was determined by X-ray diffraction. A red plate-like crystal was monoclinic, space group <I>P</I>2<SUB>1</SUB>, <I>a</I>=12.401 (2), <I>b</I>=9.9400 (7), <I>c</I>=10.932 (1) Å, β=108.44 (1)°, and <I>Z</I>=2. The structure was refined to <I>R</I>=0.047 on 2818 reflections. The geometrical isomers were compared sepectroscopically.
著者
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SATO Shoichi
The Institure for Solid State Physics, The University of Tokyo
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Yoshikawa Yuzo
Department Of Chemistry Faculty Of Science Okayama University
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NAKANO Yoshiharu
Department of Chemistry, Faculty of Science, Ibaraki University
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SATO Shoichi
The Institute for Solid State Physics, The University of Tokyo
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Masuhara Shigeo
Department of Chemistry, Faculty of Science, Ibaraki University
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