The Crystal Structure of a Colored Complex, C<SUB>7</SUB>H<SUB>7</SUB>OHg·C<SUB>7</SUB>H<SUB>6</SUB>O<SUB>2</SUB>N, Obtained in the Millon Reaction of <I>p</I>-Cresol

スポンサーリンク

概要

• 論文の詳細を見る

• The crystal structure of the complex of 2-mercuri-4-methylphenol and 2-nitroso-4-methylphenol obtained in the modified Millon reaction was determined using three-dimensional X-ray diffraction data. The complex crystallizes in triclinic system, space group <I>P</I>\bar1, with a unit cell of dimensions <I>a</I>=10.26 Å, <I>b</I>=22.71 Å, <I>c</I>=5.61 Å, α=97.2°, β=93.1°, γ=91.1°, containing four complex molecules. Each of the two crystallographycally independent complex molecules both having essentially the same structure, forms a dimer with its nearest neighbor related by a center of symmetry through a pair of hydrogen bonds. The mercury atoms adopt a planar four-fold coordination with nitrogen, carbon and two oxygen atoms.

• 公益社団法人 日本化学会の論文

著者

• Kobayashi Yoshiko

  Faculty of Pharmaceutical Sciences, The University of Tokyo

関連論文

• The Crystal Structure of a Colored Complex, C7H7OHg·C7H6O2N, Obtained in the Millon Reaction of p-Cresol

スポンサーリンク