Addition of Tellurium Tetrachloride to Olefins and Pyrolysis of the Adduct

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概要

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• The tellurium tetrachloride-cyclohexene adduct, 2-chlorocyclohexyltellurium trichloride (I) and bis(2-chlorocyclohexyl) tellurium dichloride (II), both gave, on pyrolysis, chlorocyclohexane as the chlorinated compound. An intermolecular hydrogen transfer is required for the formation of chlorocyclohexane from I. Chloro-<I>n</I>-propyltellurium trichloride (III) and bis(chloro-<I>n</I>-propyl)-tellurium dichloride (IV) were formed by the addition of tellurium tetrachloride to propylene. The pyrolysis of III afforded allyl chloride, 1,2-dichloropropane, and hydrogen chloride, while tellurium was simultaneously reduced. Besides these products, isopropyl chloride was also obtained from IV. Some properties of the adduct and the effect of the temperature on the thermal decomposition were studied.

• 公益社団法人 日本化学会の論文

著者

• Ogawa Masao

  Central Research Laboratory, Showa Denko K. K.

• Ishioka Ryoji

  Central Research Laboratory, Showa Denko K. K.

関連論文

• Addition of Tellurium Tetrachloride to Olefins and Pyrolysis of the Adduct

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