Chromatographic Resolution of Several Racemates by Means of Optically Active Acidic Polymers Derived from α-Amino Acids
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概要
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The chromatographic resolution of several racemic amines was investigated by using three types of copolymers composed by <I>N</I>-acroylated α-amino acid and <I>N</I>,<I>N</I>′-dimethacroylhexamethylenediamine. The anilides of DL-phenylalanine and DL-valine, and of DL-phenylglycine and DL-1,2-diphenylethylamine, were partially resolved. The combination of substrate and sorbent giving the most efficient resolution was anilide of phenylglycine and the copolymer involving L-phenyl-alanine.
- 公益社団法人 日本化学会の論文
著者
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Yamashita Tetsushi
Faculty of Science, Osaka City University
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Nakamura Nobuo
Faculty of Science, Osaka City University
関連論文
- Ferroelectric Phase Transition in Ammonium Hydrogen Bis (Chloroacetate) : I. Nuclear Quadrupole Resonance in NH_4H(ClCH_2COO)_2 and ND_4D(ClCH_2COO)_2
- Chromatographic Resolution of Several Racemates by Means of Optically Active Acidic Polymers Derived from α-Amino Acids