Geometric Configurations of α-Cyano-β-methyl-β-alkylglycidic Esters
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概要
- 論文の詳細を見る
α-Cyanoglycidic ester derivatives have been prepared from alkylidenecyanoacetic esters with hydrogen peroxide. The NMR technique has been applied to the study of the geometric configurations of the stereoisomeric mixture of the glycidic esters. It has been found that the β-methyl protons <I>cis</I> to the ester group respond at a higher field than do the <I>trans</I> protons.
- 公益社団法人 日本化学会の論文
著者
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IGARASHI Minoru
Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology and CREST, Japan Science and Technology Corporation (JST)
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Akano Makiko
The Institute of Physical and Chemical Research
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Fujimoto Akira
The Institute of Physical and Chemical Research
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Midorikawa Hiroshi
The Institute of Physical and Chemical Research
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