A Convenient Method for the Preparation of Primary Amines by the Use of Bisbenzenesulfenimide and Bis-<I>p</I>-chlorophenylsulfenimide
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概要
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A convenient method for the preparation of primary amines by the use of bisarylsulfenimide has been established. Primary amines were obtained in good yields under mild reaction conditions by treating <I>N</I>-substituted bisarylsulfenimides with hydrochloric acid or mercaptan. The <I>N</I>-substituted bisarylsulfenimides were prepared in good yields by the reactions of lithium bisarylsulfenimide with alkyl halides or alkyl <I>p</I>-toluenesulfonates or by the addition reactions of bisarylsulfenimide to olefinic compounds.
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関連論文
- The Reactions of Phosphonium Ylides and Oxosulfonium Methylide with Sulfenamide Derivatives
- A Convenient Method for the Preparation of Primary Amines by the Use of Bisbenzenesulfenimide and Bis-p-chlorophenylsulfenimide