Studies of Phosphorylation. V. The Synthesis of Inosine-5′-thiophosphates

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概要

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• Two isomers of inosine-5′-thiophosphates, inosine-5′-phosphorothionate and 5′-deoxy-5′-thioinosine-5′-phosphorothioate, were synthesized by the direct phosphorylation of inosine with phosphorus thiochloride, and by the treatment of 5′-deoxy-5′-iodoinosine with trisodium phosphorothioate, respectively. The structure of the thiophosphate residues was identified by means of <SUP>31</SUP>P NMR. The flavoring activities of these thiophosphates were measured as the synergistic strength with monosodium glutamate; it was found that the strength of each compound was lower than that of inosine-5′-phosphate.

• 公益社団法人 日本化学会の論文

著者

• Kainosho Masatsune

  Central Research Laboratories, Ajinomoto Co., Inc.

• Haga Kazuko

  Central Research Laboratories, Ajinomoto Co., Inc.

関連論文

• Studies of Phosphorylation. V. The Synthesis of Inosine-5′-thiophosphates
• Conformation of α-Aminobutyric Acid in Aqueous Solution

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