Synthesis and the Iodine-Catalyzed Rearrangement of Isohibaene

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概要

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• A partial synthesis of isohibaene (VI) starting with nezukol (V) has been accomplished. It involves, as the key step, the intramolecular insertion reaction of a ketocarbene generated by cuprous oxide-catalyzed decomposition of diazoketone (XI) under irradiation. It has been found that isohibaene undergoes rearrangement into a mixture of phyllocladene (XIV) and isophyllocladene (XV) by iodine catalytically.

• 公益社団法人 日本化学会の論文

著者

• Yoshikoshi Akira

  Chemical Research Institute Of Non-aqueous Solutions Tohoku University

• Kitadani Masayuki

  College of General Education, Kobe University

• Ito Ken

  College of General Education, Kobe University

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