Infrared Spectroscopic Study of Enol and Enol Derivatives Coordinated to Platinum(II) and Palladmm(II)

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概要

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• The infrared spectra of [Cl<SUB>2</SUB>M Olefin]<SUB>2</SUB> (olefin=vinyl alcohol, vinyl ethers, and their derivatives, M=Pt and Pd) have been studied in the 4000–100 cm<SUP>−1</SUP> frequency region. A normal coordinate analysis of the coordinated vinyl alcohol indicated that the lone-pair electrons of oxygen conjugated with π-electrons of the double bond to some extent, even in the coordinated state. The coordination strengths of vinyl alcohol, vinyl ethers, and their derivatives have been examined by comparing the metal-olefin streching vibrations.

• 公益社団法人 日本化学会の論文

著者

• Nozakura Shun-ichi

  Faculty of Science, Osaka University

• Wakatsuki Yasuo

  Faculty of Science, Osaka University

• Murahashi hunsuke

  Faculty of Science, Osaka University

関連論文

• Infrared Spectroscopic Study of Enol and Enol Derivatives Coordinated to Platinum(II) and Palladmm(II)

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