γ-Induced Addition of Trialkyltin Hydrides to Unsaturated Esters

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概要

• 論文の詳細を見る

• γ-Induced hydrostannation of ethyl acrylate, allyl acetate, and vinyl acetate with triethyltin and tri-<I>n</I>-butyltin hydrides was attempted. The hydrostannation of ethyl acrylate and allyl acetate gave the corresponding adducts in almost quantitative yield. (2-Acetoxyethyl)-tri-<I>n</I>-butyltin expected from hydrostannation of vinyl acetate with tri-<I>n</I>-butyltin hydride could not be isolated. However, NMR and IR spectra indicated the formation of the adduct, which was found to decompose into ethylene and tri-<I>n</I>-butyltin acetate. The decomposition of the adduct was discussed in comparison with other adducts.

• 公益社団法人 日本化学会の論文

著者

• Fukumoto Tsugio

  Department of Chemistry Radiation Center of Osaka Prefecture

• Nakao Ren

  Department of Chemistry, Radiation Center of Osaka Prefecture

• Tsurugi Jitsuo

  Department of Chemistry, Radiation Center of Osaka Prefecture

• Murata Niro

  Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture

• Iida Masaru

  Department of Applied Chemistry, University of Osaka Prefecture

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• The Deacylation of β-Diketones in the Presence of Copper(II)-β-Diketonates in Methanol
• γ-Induced Addition of Trialkyltin Hydrides to Unsaturated Esters
• The Accelerated Reaction of 2,2-Diphenyl-1-picrylhydrazyl with Cupric 3-(1-Butenyl)-2,4-pentanedionate in Frozen Solutions and Its ESR Spectra

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