The X-Ray Emission Spectra of the Compounds of Third-period Elements. I. The <I>K</I> Spectra of Chlorine in Compounds

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概要

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• On chlorine gas and several oxysalts of chlorine, the values of the wavelength shift of Cl<I>K</I>α<SUB>1,2</SUB> lines and the spectra of Cl<I>K</I>β lines were measured. We thus verified our assumption that the <I>K</I>β′ line results from the bias of valence electrons from the atom of the third-period element to the oxygen atom in the oxyanion; this can be explained in terms of the relationship between the chemical structure and the Cl<I>K</I>β spectrum of the hypochlorite ion. The relationship between the relative intensity of the <I>K</I>β′ line and the wavelength shift of the <I>K</I>α<SUB>1,2</SUB> lines was linear, just as in the cases of oxygen-sulfur compounds.

• 公益社団法人 日本化学会の論文

著者

• Takahashi Yoshihito

  Government Industrial Development Laboratory, Hokkaido

• Takahashi Yoshihito

  Government Industrial Development Laboratory

関連論文

• The X-Ray Emission Spectra of the Compounds of Third-period Elements. I. The K Spectra of Chlorine in Compounds

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