The Protonation of Aromatic Hydrocarbon Radical Anions. I. A Comparison of Methods and a Study of the Mechanism

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概要

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• The protonation mechanism of the aromatic hydrocarbon radical anions, such as biphenyl, naphthalene, phenanthrene, anthracene, 1,2-benzanthracene, and pyrene, in dimethylformamide (DMF) and water mixtures was studied. Three methods of measuring the concentration of the radical anions, <I>i.e.</I> polarography and ESR and UV absorption spectroscopy, were compared with each other by making simultaneous measurements of the same anthraquinone radical anion solution. A good linear relation of the polarographic anodic diffusion current to the UV absorbance was found, while the ESR signal intensity had linear relations with neither of the others in the system which contained an excessive number of parent molecules, 2×10<SUP>−3</SUP>M. The change in the visible absorption spectra of the aromatic hydrocarbon radical anions as a function of the time suggested that all the aromatic hydrocarbon radical anions decay by a first-order reaction. As a result, the radical anions were considered to decay through the following sequence:<BR>R<SUP>\newdot</SUP>+H<SUB>2</SUB>O\overset<I>k</I>→RH<SUP>·</SUP>+OH<SUP>−</SUP>, RH<SUP>·</SUP>+R<SUP>\newdot</SUP>\rightleftharpoonsRH<SUP>−</SUP>+R, and RH<SUP>−</SUP>+H<SUB>2</SUB>O\overset<I>k</I>′→RH<SUB>2</SUB>+OH<SUP>−</SUP>.

• 公益社団法人 日本化学会の論文

著者

• Fujihira Masamichi

  Institute of Industrial Science, The University of Tokyo

• Hayano Shigeo

  Institute of Industrial Science, The University of Tokyo

関連論文

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