Pd(II) Complexes with 2,2′-Diaminobiphenyl
スポンサーリンク
概要
- 論文の詳細を見る
The new palladium (II) complexes with 2,2′-diaminobiphenyl (DABP) have been synthesized under various conditions. The hexa-coordinated palladium complex, [Pd(DABP)<SUB>2</SUB>Cl<SUB>2</SUB>], has been prepared under a high pressure. The square planar diamagnetic complexes, [Pd(DABP)<SUB>2</SUB>]X<SUB>2</SUB> (X=Cl, Br), have been synthesized under atmospheric pressure. As to the [Pd(DABP)<SUB>2</SUB>]Cl<SUB>2</SUB> complexes, two isomers, the yellow complex and the yellow-green complex, are obtained according to the temperature at which the complexes are synthesized. Both the complexes, the yellow and the yellow-green complexes, are similar with respect to the powder X-ray diffraction pattern and the IR spectra in the region from 4000 cm<SUP>−1</SUP> to 200 cm<SUP>−1</SUP>, but are somewhat different with respect to the stability to air, the thermal stability, and the solubility in chloroform.
- 公益社団法人 日本化学会の論文
著者
-
Onaka Satoru
Department Of Chemistry Nagoya Institute Of Technology
-
Onaka Satoru
Department of Chemistry, Faculty of Science, The University of Tokyo
関連論文
- A Novel Au_ Supramolecule Composed of Two-, Three-, and Four-coordinated Au(I) Centers Constructed on the S_3 Scaffolding
- Synthesis and Characterization of the Au_ Cluster with Sterically Demanding Phosphine Ligands by Single Crystal X-ray Diffraction and XPS Spectroscopy
- The First Luminescent Anionic Bis(ethynylphenanthroline)gold(I) Complex
- Synthesis of Higher-Nuclearity Clusters by Use of Small Cluster Units as Building Blocks: Synthesis and X-Ray Structure Analysis of [CICCo_3(CO)_8]_2(μ-dppe) and [CICCo_3(CO)_7][CICCo_3(CO)_8](μ-TRIPHOS)(dppe=1,2-bis(diphenylphosphino) ethane; TRIPHOS=bis
- Synthesis of Higher-nuclearity Clusters by Use of Small Cluster Units as Building Blocks. Syntheses and X-Ray Analyses of p-[Co_3(CO)_9C]_2C_6H_4 and [CH_3CCo_3(CO)_8]_2(μ-dppfe)
- Construction of a Crystalline Tetramer and Infinite Network through the Dual Use of Au(I)・・・Au(I) and π-π Interactions
- Photochemistry of metal-metal bonded compounds. I. Isolation and X-ray molecular structure analyses of orthometalated triphenyl phosphite manganese carbonyl derivatives and reaction mechanisms of orthometalation from photodegradation of manganese carbonyl
- 17O NMR studies on a series of manganese carbonyl derivatives with Sn-Mn bond(s).
- 55Mn Nuclear Magnetic Resonance Studies of the Compounds with Manganese-Tin Bonds
- Pd(II) Complexes with 2,2′-Diaminobiphenyl
- 17O NMR study of metal carbonyl cluster compounds. IV. The substituent effect on the 17O NMR chemical shifts for a series of tri-nuclear metal carbonyl cluster compounds.
- 119Sn-Mössbauer and 1H- and 55Mn-NMR Spectroscopic Studies of a Series of Compounds, R3−xXxSn-Mn(CO)5
- The Syntheses of R3Sn–Mn(CO)5−nLn(n=0 or 1) Compounds and Their 119Sn-Mössbauer and 1H-NMR Studies