Photolyses of Ethoxalyl Azide in Alcohols and in Hydrocarbons Reactions of Ethoxalylnitrene

スポンサーリンク

概要

• 論文の詳細を見る

• The photolysis of ethoxalyl azide gives ethoxalylnitrene and ethoxycarbonyl isocyanate. The nitrene adds to C=C double bonds and is inserted into O–H and C–H bonds. At high ethanol concentrations, where the singlet nitrene predominates, the O–H insertion product is formed dominantly. At low ethanol concentrations, where much of the nitrene changes to the triplet state, the hydrogen-abstraction product is preferred. The reactivity of the nitrene toward the C–H bonds of 2-methylbutane is more selective than that of ethoxycarbonylnitrene.

• 公益社団法人 日本化学会の論文

著者

• Lwowski Walter

  Research Center, New Mexico State University

• Shingaki Tadao

  Institute of Chemistry, College of General Education, Osaka University

• Inagaki Masao

  Institute of Chemistry, College of General Education, Osaka University

• Takebayashi Matsuji

  Institute of Chemistry, College of General Education, Osaka University

関連論文

• Ethoxalylnitrene
• Photolyses of Ethoxalyl Azide in Alcohols and in Hydrocarbons Reactions of Ethoxalylnitrene
• Reaction of 9-diazofluorene with 2,3-dichloro-5,6-dicyano-p-benzoquinone: The structure and the behaviors of the resulting product.
• Formations and reactions of cation radicals from compounds possessing a p-dimethylaminophenyl group by reactions with o-sulfobenzoic anhydride.

スポンサーリンク