A Consideration of Orbital Interaction in the Reaction of <SUP>1</SUP><I>Δ<SUB>g</SUB></I> Molecular Oxygen with Ethylene Derivatives
スポンサーリンク
概要
- 論文の詳細を見る
The stereochemical path of the reaction between the <SUP>1</SUP><I>Δ<SUB>g</SUB></I> oxygen molecule and ethylene was examined in terms of orbital interaction. The results here obtained suggest that a path <I>via</I> the perepoxide intermediate or <I>via</I> a perepoxide-like transition state should be carefully examined in discussing not only the steric path to dioxetane, but also the mechanism of hydroperoxide formation.
- 公益社団法人 日本化学会の論文
著者
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Fukui Kenichi
Faculty of Engineeering Kyoto University
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Fujimoto Hiroshi
Faculty of Engineering, Kyoto University
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Yamabe Shinichi
Faculty of Engineering, Kyoto University
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Inagaki Satoshi
Faculty of Engineering, Kyoto University
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