The Electric Conductivity of the H<SUB>2</SUB>O-B<SUB>2</SUB>O<SUB>3</SUB> Melt

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概要

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• Electric conductivity was measured over the whole composition range of H<SUB>2</SUB>O–B<SUB>2</SUB>O<SUB>3</SUB> in the liquid state. A peculiar conductivity-temperature relation was observed in a low B<SUB>2</SUB>O<SUB>3</SUB>-to-intermediate composition. The equivalent conductance of H<SUB>3</SUB>BO<SUB>3</SUB> increases with its content in this range. Both the concentration of proton and its mobility through the proton-jump mechanism seem to change with the composition. The comparison of the results in the B<SUB>2</SUB>O<SUB>3</SUB>-rich range with those of alkali borates indicates a low extent of the dissociation of the –B–O–H group.

• 公益社団法人 日本化学会の論文

著者

• Kodama Hiroshi

  National Institute For Environmental Studies:institute For Environmental Sciences University Of Tsuk

• Yokokawa Toshio

  Faculty of Science, Hokkaido University

• Kodama Hiroshi

  National Institute for Research in Inorganic Materials

• Niwa Kichizo

  Faculty of Science, Hokkaido University

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• The Electric Conductivity of the H2O-B2O3 Melt

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