Transfer-hydrogenation and Transfer-hydrogenolysis. I. Transfer-hydrogenation of Cyclooctadienes Catalyzed by Dichlorobis(triphenylphosphine)iron(II)

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概要

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• Hydrogen transfer from a number of organic compounds to olefins in a homogeneous system was studied. In the case of hydrogen transfer to 1,5-cyclooctadiene, using dichlorobis(triphenylphosphine)iron(II) as the catalyst, dihydroxybenzenes, such as pyrocatechol and hydroquinone, were much superior to <I>prim</I>- and <I>sec</I>-alcohols, 1-dodecanethiol, and cyclohexene as hydrogen donors.

• 公益社団法人 日本化学会の論文

著者

• FUKUZUMI Kazuo

  Department of Applied Chemistry, Faculty of Engineering, Nagoya University

• Nishiguchi Takeshi

  Department of Applied Chemistry, Faculty of Engineering, Nagoya University

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