The Vibrational Spectra of Water of Crystallization in Barium Chlorate Monohydrate, Calcium Sulfate Dihydrate and Copper Chloride Dihydrate Crystals
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Infrared spectra of water of crystallization and heavy water of crystallization were mesasured for Ba(ClO<SUB>3</SUB>)<SUB>2</SUB>·H<SUB>2</SUB>O, CaSO<SUB>4</SUB>·2H<SUB>2</SUB>O, CuCl<SUB>2</SUB>·2H<SUB>2</SUB>O, Ba(ClO<SUB>3</SUB>)<SUB>2</SUB>·D<SUB>2</SUB>O, CaSO<SUB>4</SUB>·2D<SUB>2</SUB>O, and CuCl<SUB>2</SUB>·2D<SUB>2</SUB>O, in which the divalent metal ion lies on the bisector line of H–O–H angle or D–O–D angle. From a comparison of the spectra, assignment of the infrared absorption bands was made for the rotational and the translational vibrations of the water of crystallization.
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