The Viscosities of Aqueous Solutions Containing Metal Complexes. III. Iminodiacetato and Methyliminodiacetato Complexes

スポンサーリンク

概要

• 論文の詳細を見る

• The viscosities of aqueous solutions containing a metal chelate formed with iminodiacetic acid (H<SUB>2</SUB>ida) or <I>N</I>-methyliminodiacetic acid (H<SUB>2</SUB>mida) were measured with Cannon-Fenske capillary viscometers. Measurements were made in a Shibata viscosity bath maintained at 25±0.01°C. The Jones-Dole viscosity <I>B</I>-coefficient of each bis-ida chelate is lower than that of the corresponding bis-mida chelate, as may be expected. The <I>B</I>-coefficients for the mono-ida and mono-mida chelates were not determined accurately and will not be reported here. The <I>B</I>-value of <I>cisN</I>-[Co(ida)<SUB>2</SUB>]<SUP>−</SUP> is higher than that of the <I>trans</I>-isomer. This is probably associated with the fact that the <I>cis</I>-isomer interacts with the solvent more strongly than the <I>trans</I>-isomer.

• 公益社団法人 日本化学会の論文

著者

• Mizutani Kiyoshi

  Department of Chemistry, College of General Education, Nagoya University

• Yasuda Motoo

  Department of Chemistry, College of General Education, Nagoya University

関連論文

• The volume, adiabatic compressibility, and viscosity of amino acids in aqueous alkali-chloride solutions.
• The Viscosities of Aqueous Solutions Containing Metal Complexes. III. Iminodiacetato and Methyliminodiacetato Complexes
• Apparent Molal Volumes of Urea and Its Derivatives in Aqueous Alkali Chloride Solutions.
• Volume and adiabatic compressibility of amino acids in urea-water mixtures.
• Apparent molal volumes of urea derivatives in water-methanol mixtures.

スポンサーリンク