Molecular Complexes of Arenetricarbonylchromium

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概要

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• Arenetricarbonylchromium forms a charge-transfer molecular complex with electron acceptors such as 1,3,5-trinitrobenzene and tetracyanoethylene but not with electron donors such as <I>N</I>,<I>N</I>,<I>N</I>′,<I>N</I>′-tetramethyl-<I>p</I>-phenylenediamine. The ionization potentials of arenetricarbonylchromium complexes were determined from the charge-transfer transition energies in the molecular complexes. The molecular complexes are formed by a charge-transfer interaction of electron acceptor toward the π-coordinating benzene ring of arenetricarbonylchromium in the case of 1,3,5-trinitrobenzene, and by a charge-transfer toward the central chromium in the case of tetracyanoethylene.

• 公益社団法人 日本化学会の論文

著者

• Kaizu Youkoh

  Department of Chemistry, Tokyo Institute of Technology

関連論文

• Molecular Complexes of Arenetricarbonylchromium

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