Thermometric Titration in the Investigation of the Formation of Polyanions of Molybdenum(VI), Tungsten(VI), Vanadium(V), and Chromium(VI). III. Titration of Molybdic Acid with Sodium Hydroxide Solution

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概要

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• To define the properties of molybdenum-containing species which appear in the acidification of neutral molybdate solution with mineral acid, the reverse process, <I>i.e.</I> the titration of molybdic acid of acidified molybdate solution with sodium hydroxide, was examined and the titration curves were obtained thermometrically as well as potentiometrically. In the thermometric titration curves there are inflections not found on the pH-titration curves of the same systems. Titration curves of both methods change with molybdenum concentration, the reaction process being found to be responsible for the change. Polymolybdate anions were identified with the aid of the ultraviolet spectrophotometry of Punger <I>et al.</I> A neutral salt such as sodium perchlorate or lithium perchlorate was found to affect the shape of the thermometric titration curve, since in the presence of such salt octamolybdate ion was readily converted into heptamolybdate ion.

• 公益社団法人 日本化学会の論文

著者

• Kiba Nobutoshi

  Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

関連論文

• Thermometric Titration in the Investigation of the Formation of Polyanions of Molybdenum(VI), Tungsten(VI), Vanadium(V), and Chromium(VI). III. Titration of Molybdic Acid with Sodium Hydroxide Solution

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