The Reactions of Stannic Halides with Some Triphenylphosphine, -arsine and -stibine-substituted Iron Carbonyls

スポンサーリンク

概要

• 論文の詳細を見る

• The reactions of stannic chloride and bromide with triphenylphosphine, -arsine and -stibine tetracarbonyl iron(0) undergo oxidative-elimination reactions to afford new binuclear organometallic compounds in good yields; Fe(CO)<SUB>4</SUB>EPh<SUB>3</SUB>+SnX<SUB>4</SUB>→Fe(CO)<SUB>3</SUB>EPh<SUB>3</SUB>SnX<SUB>4</SUB>+CO (E=P, As, Sb; X=Cl, Br; Ph=C<SUB>6</SUB>H<SUB>5</SUB>), where one molecule of carbon monoxide is discharged. The complexes are characterized by elemental analysis, by infrared and Mössbauer spectroscopies, and by conductivity measurements; these data are used to predict their possible formulation as nonionic, hexa-co-ordinate iron derivatives of the Fe(CO)<SUB>3</SUB>(X)(EPh<SUB>3</SUB>)(SnX<SUB>3</SUB>) type containing a tin-to-iron metal-metal bond.

• 公益社団法人 日本化学会の論文

著者

• Takano Tetsuo

  Department of Chemisjry, Faculty of Science, The University of Tokyo

関連論文

• The Reactions of Stannic Halides with Some Triphenylphosphine, -arsine and -stibine-substituted Iron Carbonyls

スポンサーリンク