Polarographic Behavior of 9-Nitroanthracene and 9,10-Dinitroanthracene in Dimethylformamide
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概要
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The polarographic behavior of 9-nitroanthracene and 9,10-dinitroanthracene has been studied in dimethylformamide. 9-Nitroanthracene shows consecutive two one-electron diffusion-controlled reduction waves followed by fast chemical reactions. 9,10-Dinitroanthracene, however, shows only one reversible two-electron diffusion-controlled wave. The effect of the supporting electrolyte cation on these reduction waves was also investigated. In alkali metal or alkaline earth metal perchlorate as a supporting electrolyte, the half-wave potentials shift to the anodic side. The relationship between the half-wave potential and the ionic potential of the cation was discussed.
- 公益社団法人 日本化学会の論文
著者
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Ichimura Akio
Department Of Chemistry Faculty Of Science Osaka City University
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Kitagawa Toyokichi
Department of Chemistry Faculty of Education Kobe University
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