Dielectric Relaxation and Molecular Structure. IV. Dielectric Relaxation and Hydrogen Bonding in Chloroanilines

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概要

• 論文の詳細を見る

• Measurements of relative permittivity were carried out at 30.0 °C in <I>p</I>-dioxane at 1 MHz and at 9.48 GHz for <I>ortho</I> (A), <I>meta</I> (B), and <I>para</I> (C) chloroanilines. The results are interpreted in terms of hydrogen bonding between amino hydrogens and the oxygen atoms of the dioxane molecule, the dipole moments and dielectric relaxation time values being given. The relative behaviour of chloroanilines has been discussed. It seems that a finite probability of H–Cl bond formation exists between one of the amino hydrogens and the neighbouring chlorine atom in <I>o</I>-chloroaniline.

• 公益社団法人 日本化学会の論文

著者

• Srivastava K.

  Physics Department, Panjab University

• Vij J.

  Physics Department, Panjab University

• Vij J.

  Physics Department, Panjabi University

関連論文

• Dielectric Relaxation and Molecular Structure. III. Dielectric Relaxation Study of Some Anilines in Benzene Solutions at Different Temperatures
• Dielectric Relaxation and Molecular Structure. IV. Dielectric Relaxation and Hydrogen Bonding in Chloroanilines

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