Stereospecific Syntheses and Acid Dissociations of 2,3-Diaminotetralins and 2,3-Diamino-<I>trans</I>-decalins
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概要
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<I>cis</I>- and <I>trans</I>-2,3-Diaminotetralins and 2(<I>e</I>), 3(<I>e</I>)-, 2(<I>e</I>), 3(<I>a</I>)-, and 2(<I>a</I>), 3(<I>a</I>)-diamino-<I>trans</I>-decalins were stereospecifically synthesized from 1,4-dihydronaphthalene and <I>trans</I>-<I>Δ</I><SUP>2</SUP>-octalin, respectively. The stepwise acid dissociation constants of the decalin derivatives were determined by potentiometric method and discussed in relation to their configurations.
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