The Formation and Chelate–forming Properties of 2-Chloriminocyclohexanone Oxime and Its Hydrochloride

スポンサーリンク

概要

• 論文の詳細を見る

• Cyclohexane-1,2-dione dioxime (<B>1</B>) in absolute ethanol containing hydrogen chloride was subjected to an irreversible dehydration to afford 2-chloriminocyclohexanone oxime hydrochloride (<B>2</B>), which could be liberated by cautious neutralization with sodium carbonate. The novel free and salt-form compounds thus obtained reacted with metal ions, such as Cu(II), Co(II), Ni(II), and Pd(II), to afford stable complexes. The molar ratio and the consecutive stability constants of a Ni(II) complex of <B>2</B> were determined and compared with those of a complex of <B>1</B> with Ni(II). An approximate linear relationship between the logarithm of the rate constant of the <I>N</I>-chlorimination and the acidity function, <I>H</I><SUB>0</SUB>, was observed.

• 公益社団法人 日本化学会の論文

著者

• Kobayashi Yoshinari

  Chemicals Research and Development Laboratories, Toray Industries, Inc.

• Wakamatsu Shigeru

  Chemicals Research and Development Laboratories, Toray Industries, Inc.

関連論文

• The Formation and Chelate–forming Properties of 2-Chloriminocyclohexanone Oxime and Its Hydrochloride

スポンサーリンク