Transference of Water to the Nitrobenzene Phase for the Extraction of Tris(1,10-phenanthroline)iron (II) and Tris(2,2′-bipyridine)iron(II) Chelate Salts
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概要
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The amount of water transferred to the nitrobenzene phase was determined for the extraction of ion pairs of tris(1,10-phenanthroline)iron(II) and tris(2,2′-bipyridine) iron(II) with halide and pseudohalide anions. For both chelate systems the smaller the anion, the greater the amount of water transported, very similar results being obtained for a common anion. The results were discussed in relation to water of crystallization, extractability and temperature effect.
- 公益社団法人 日本化学会の論文
著者
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Yamamoto Yuroku
Department Of Chemistry Faculty Of Science Hiroshima University
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Tarui Takao
Department Of Chemistry Faculty Of Science Kumamoto University
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Tarumoto Tsunehiko
Department of Chemistry, Faculty of Science, Hiroshima University
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- Transference of Water to the Nitrobenzene Phase for the Extraction of Tris(1,10-phenanthroline)iron (II) and Tris(2,2′-bipyridine)iron(II) Chelate Salts