Radioactive Iodine Exchange and the Dushman Reaction

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概要

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• Critical studies were made on the Dushman reaction, 6H<SUP>+</SUP>+5I<SUP>−</SUP>+IO<SUB>3</SUB><SUP>−</SUP>=3I<SUB>2</SUB>+3H<SUB>2</SUB>O. Rate measurements of radioactive iodine exchange away from chemical equilibrium gave results which made the rate law for the Dushman reaction doubtful. Measurements of d(H<SUP>+</SUP>)/d<I>t</I> confirmed the rate law. The contrary interpretation resulted because existing chemical information was not considered. This situation holds in many radioactive iodine exchange experiments done on the Dushman reaction.

• 公益社団法人 日本化学会の論文

著者

• Furuichi Ryusaburo

  Department of Applied Chemistry, Faculty of Engineering, Hokkaido University

• Liebhafsky Herman

  Department of Chemistry, Texas A & M University, College Station

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