The Allylic Rearrangement of Linalyl Acetate in the Medium of Acetic Acid, Propionic Acid, or Acetic Acid Containing Dioxane or Sulfuric Acid
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概要
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The mechanism of the allylic rearrangement of linalyl acetate in the medium of acetic acid, propionic acid, or acetic acid containing dioxane or sulfuric acid has been investigated. The nature of the carbonium-ion pairs generated from linalyl acetate in low-dielectric-constant solvents or in strong acids, and the behavior of the active intermediate in the transition state were postulated from the kinetic data as well as from the physicochemical properties and distributions of the products.
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