The Reaction of α-Olefins and Epoxyalkanes with the Dimethyl Sulfide–Sulfur Trioxide Complex

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概要

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• 2-Dimethylsulfonioalkane-1-sulfonates were formed by the reaction of α-olefins with the dimethyl sulfide-sulfur trioxide complex. The treatment of these products with alkali gave <I>Δ</I><SUP>1</SUP>-alkene-1-sulfonates quantitatively. In the reaction between 1,2-epoxyalkanes and the dimethyl sulfide-sulfur trioxide complex, 1-dimethylsulfoniomethyl-1-alkyl sulfate was formed exclusively. 1-Dimethylsulfonio-1-alkenes were quantitatively formed upon the treatment of these products with alkali. The chemical structures of these compounds have been established, and the reaction routes were discussed.

• 公益社団法人 日本化学会の論文

著者

• Nagayama Masuzo

  Central Research Laboratories, Lion Fat & Oil Co., Ltd.

• Yaguchi Katsumi

  Central Research Laboratories, Lion Fat & Oil Co., Ltd.

• Okumura Osamu

  Central Research Laboratories, Lion Fat & Oil Co., Ltd.

• Mori Akira

  Central Research Laboratories, Lion Fat & Oil Co., Ltd.

• Okumura Osamu

  Central Research Laboratories, Lion Fat & Oil Co., Ltd.

関連論文

• The Reaction of α-Olefins and Epoxyalkanes with the Dimethyl Sulfide–Sulfur Trioxide Complex
• The Mechanism for the Sulfonation of Olefins with a Sulfur Trioxide–Dioxane Complex

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