Vibrational Spectra and Normal Coordinate Analysis of Bis(methylthio)mercury
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The IR and Raman spectra of bis(methylthio)mercury and methyl(methylthio)mercury were studied. Fundamental vibrations were assigned as follows: frequencies 698, 330, 530 and 174 cm<SUP>−1</SUP> to C–S stretching, S–Hg stretching, C–Hg stretching and C–S–Hg bending vibrations, respectively. The fundamental vibrations were confirmed by normal coordinate analysis. The force constants of S–C and S–Hg stretching vibrations were estimated to be 2.16 and 1.5 md/Å, respectively.
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- Vibrational Spectra and Normal Coordinate Analysis of Bis(methylthio)mercury