Inositol Derivatives. 7. Azidolysis of Disulfonates of <I>myo</I>-Inositol and 1,2-<I>O</I>-CyclohexyIidene Derivative
スポンサーリンク
概要
- 論文の詳細を見る
Reactions of azide ion with three disulfonates (1,4-, 1,5-, and 1,6-) of <I>myo</I>-inositol and its 1,2-<I>O</I>-cyclohexylidene derivative were studied. The structures of the new azido compounds thus obtained were established by PMR spectroscopy and reaction sequences. The reaction mechanisms of the neighboring-group participation reactions were discussed. Hydrogenation of the azido compounds followed by acetylation afforded the corresponding six inosadiamines as their hexaacetates: three known (<I>allo</I>-1,5, <I>muco</I>-1,3, and <I>myo</I>-4,5) and three hitherto unknown inosadiamines (<I>allo</I>-1,4, <I>muco</I>-1,2, and <I>chiro</I>-2,4).
- 公益社団法人 日本化学会の論文
著者
関連論文
- Strong ground motions recorded by a near-source seismographic array during the 16 August 2005 Miyagi-Ken-Oki, JAPAN, earthquake (Mw7.2)
- Maternal and Neonatal Factors Associated with the High Yield of Mononuclear Low-Density/CD34^+ Cells from Placental/Umbilical Cord Blood
- Direct observation of rupture propagation during the 2011 off the Pacific coast of Tohoku Earthquake (M_w 9.0) using a small seismic array
- A moessbauer study of the photolysis of bis- and tris-oxalato iron(III) complexes in a solid, solutions, and frozen solutions.
- Moessbauer studies of the thermal decomposition of tris(2,2'-bipyridine)iron(II) chloride and the structures of the isomers of 2,2'-bipyridineiron(II) chloride.
- Spatial variation of lithospheric heterogeneity on the globe as revealed from transverse amplitudes of short-period teleseismic P-waves
- Strong ground motions recorded by a near-source seismographic array during the 16 August 2005 Miyagi-Ken-Oki, JAPAN, earthquake (Mw 7.2)
- Inositol Derivatives. 7. Azidolysis of Disulfonates of myo-Inositol and 1,2-O-CyclohexyIidene Derivative