The Oxyphenylation of Cyclic Olefins Conjugated to the Benzene Ring by Means of Palladium Chloride

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概要

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• The reaction of 1,2-dihydronaphthalene, indene, and acenaphthylene with phenylpalladium chloride prepared <I>in situ</I> from phenylmercuric chloride and lithium chloropalladate in aqueous acetone afforded 2-phenyltetrarol, 2-phenylindanol, and 2-phenylacenaphthenol respectively, accompanying by the corresponding phenylated olefins. Acetoxyphenylation products were also obtained in the reactions in acetic acid. The configurations of these oxyphenylated compounds were determined to be <I>trans</I>.

• 公益社団法人 日本化学会の論文

著者

• Horino Hiroshi

  College of General Education, Tohoku University

• Inoue Naoto

  College of General Education, Tohoku University

• Arai Mannosuke

  College of General Education, Tohoku University

関連論文

• The Oxidation of Chroman-4-ols with Chromic Acid
• The Oxyphenylation of Cyclic Olefins Conjugated to the Benzene Ring by Means of Palladium Chloride
• The Conformation of trans-4-Acetoxyisoflavans and Related Compounds

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